| Date | Home | Score | Away | R | Tournament |
|---|---|---|---|---|---|
| 14 Jun 1966 | Italy | 6–1 | Bulgaria | H | ITL · Friendly |
| 13 Jun 1966 | Jamaica | 0–0 | Guadeloupe | D | ITL · Friendly |
| 13 Jun 1966 | Haiti | 1–4 | Suriname | A | ITL · Friendly |
| 12 Jun 1966 | Trinidad and Tobago | 1–0 | Curaçao | H | ITL · Friendly |
| 12 Jun 1966 | Portugal | 4–0 | Norway | H | ITL · Friendly |
| 12 Jun 1966 | Brazil | 2–1 | Czechoslovakia | H | ITL · Friendly |
| 11 Jun 1966 | Haiti | 3–0 | Guadeloupe | H | ITL · Friendly |
| 11 Jun 1966 | Argentina | 1–1 | Poland | D | ITL · Friendly |
| 10 Jun 1966 | Trinidad and Tobago | 3–2 | Suriname | H | ITL · Friendly |
| 10 Jun 1966 | Curaçao | 0–0 | Jamaica | D | ITL · Friendly |
| 08 Jun 1966 | Brazil | 3–1 | Peru | H | ITL · Friendly |
| 08 Jun 1966 | Brazil | 2–1 | Poland | H | ITL · Friendly |
| 05 Jun 1966 | Russia | 3–3 | France | D | ITL · Friendly |
| 05 Jun 1966 | Hungary | 3–1 | Switzerland | H | ITL · Friendly |
| 05 Jun 1966 | Brazil | 4–1 | Poland | H | ITL · Friendly |
| 04 Jun 1966 | Brazil | 4–0 | Peru | H | ITL · Friendly |
| 01 Jun 1966 | Yugoslavia | 0–2 | Bulgaria | A | ITL · Friendly |
| 01 Jun 1966 | Germany | 1–0 | Romania | H | ITL · Friendly |
| 30 May 1966 | Denmark | 0–0 | Turkey | D | ITL · Friendly |
| 29 May 1966 | Chile | 0–1 | Mexico | A | ITL · Friendly |
| 29 May 1966 | Benin | 2–2 | Togo | D | ITL · Friendly |
| 25 May 1966 | Lithuania | 6–0 | Libya | H | ITL · Friendly |
| 25 May 1966 | Belgium | 2–3 | Republic of Ireland | A | ITL · Friendly |
| 22 May 1966 | Chile | 2–0 | Wales | H | ITL · Friendly |
| 22 May 1966 | Belgium | 0–1 | Russia | A | ITL · Friendly |
| 22 May 1966 | Austria | 1–0 | Republic of Ireland | H | ITL · Friendly |
| 19 May 1966 | Brazil | 1–0 | Chile | H | ITL · Friendly |
| 18 May 1966 | Poland | 1–1 | Sweden | D | ITL · Friendly |
| 18 May 1966 | Czechoslovakia | 1–2 | Russia | A | ITL · Friendly |
| 18 May 1966 | Brazil | 1–0 | Wales | H | ITL · Friendly |
| 15 May 1966 | Brazil | 1–1 | Chile | D | ITL · Friendly |
| 14 May 1966 | Brazil | 3–1 | Wales | H | ITL · Friendly |
| 11 May 1966 | Scotland | 0–3 | Netherlands | A | ITL · Friendly |
| 11 May 1966 | Mexico | 1–0 | Chile | H | ITL · Friendly |
| 08 May 1966 | Yugoslavia | 2–0 | Hungary | H | ITL · Friendly |
| 08 May 1966 | Finland | 0–3 | Israel | A | ITL · Friendly |
| 07 May 1966 | Northern Ireland | 0–2 | Germany | A | ITL · Friendly |
| 04 May 1966 | Republic of Ireland | 0–4 | Germany | A | ITL · Friendly |
| 04 May 1966 | England | 2–0 | Yugoslavia | H | ITL · Friendly |
| 03 May 1966 | Poland | 1–1 | Hungary | D | ITL · Friendly |
| 27 Apr 1966 | German DR | 4–1 | Sweden | H | ITL · Friendly |
| 26 Apr 1966 | Togo | 1–0 | Benin | H | ITL · Friendly |
| 24 Apr 1966 | Mexico | 7–0 | Paraguay | H | ITL · Friendly |
| 24 Apr 1966 | Austria | 0–1 | Russia | A | ITL · Friendly |
| 20 Apr 1966 | Switzerland | 2–2 | Russia | D | ITL · Friendly |
| 20 Apr 1966 | France | 0–3 | Belgium | A | ITL · Friendly |
| 17 Apr 1966 | Netherlands | 3–1 | Belgium | H | ITL · Friendly |
| 10 Apr 1966 | Benin | 2–5 | Ghana | A | ITL · Friendly |
| 09 Apr 1966 | Nigeria | 1–1 | Togo | D | ITL · Friendly |
| 06 Apr 1966 | Israel | 7–1 | Finland | H | ITL · Friendly |
| 03 Apr 1966 | Kenya | 3–3 | Uganda | D | ITL · Friendly |
| 01 Apr 1966 | Montenegro | 0–1 | Russia | A | ITL · Friendly |
| 27 Mar 1966 | Libya | 0–1 | Malta | A | ITL · Friendly |
| 25 Mar 1966 | Panama | 1–0 | El Salvador | H | ITL · Friendly |
| 23 Mar 1966 | Netherlands | 2–4 | Germany | A | ITL · Friendly |
| 19 Mar 1966 | Iraq | 1–2 | Morocco | A | ITL · Friendly |
| 19 Mar 1966 | France | 0–0 | Italy | D | ITL · Friendly |
| 18 Mar 1966 | Iraq | 0–1 | Morocco | A | ITL · Friendly |
| 16 Mar 1966 | Iran | 0–0 | Turkey | D | ITL · Friendly |
| 14 Mar 1966 | Libya | 0–2 | Iraq | A | ITL · Friendly |
| 11 Mar 1966 | Libya | 4–0 | Morocco | H | ITL · Friendly |
| 06 Mar 1966 | Togo | 2–2 | Nigeria | D | ITL · Friendly |
| 06 Mar 1966 | Morocco | 1–0 | Algeria | H | ITL · Friendly |
| 06 Mar 1966 | Guinea | 5–0 | Senegal | H | ITL · Friendly |
| 05 Mar 1966 | Uganda | 2–3 | Kenya | A | ITL · Friendly |
| 28 Feb 1966 | Panama | 0–1 | Guatemala | A | ITL · Friendly |
| 27 Feb 1966 | Niger | 2–1 | DR Congo | H | ITL · Friendly |
| 27 Feb 1966 | Benin | 1–2 | Nigeria | A | ITL · Friendly |
| 25 Feb 1966 | Egypt | 2–2 | Bulgaria | D | ITL · Friendly |
| 23 Feb 1966 | England | 1–0 | Germany | H | ITL · Friendly |
| 23 Feb 1966 | Chile | 0–2 | Russia | A | ITL · Friendly |
| 13 Feb 1966 | Malta | 1–0 | Libya | H | ITL · Friendly |
| 08 Feb 1966 | Panama | 3–1 | Nicaragua | H | ITL · Friendly |
| 05 Jan 1966 | England | 1–1 | Poland | D | ITL · Friendly |