| Date | Home | Score | Away | R | Tournament |
|---|---|---|---|---|---|
| 19 Dec 1968 | Brazil | 3β2 | Yugoslavia | H | ITL Β· Friendly |
| 17 Dec 1968 | Brazil | 3β3 | Yugoslavia | D | ITL Β· Friendly |
| 14 Dec 1968 | Brazil | 2β2 | Germany | D | ITL Β· Friendly |
| 03 Nov 1968 | Brazil | 2β1 | Mexico | H | ITL Β· Friendly |
| 31 Oct 1968 | Brazil | 1β2 | Mexico | A | ITL Β· Friendly |
| 11 Aug 1968 | Brazil | 3β2 | Argentina | H | ITL Β· Friendly |
| 07 Aug 1968 | Brazil | 4β1 | Argentina | H | ITL Β· Friendly |
| 28 Jul 1968 | Paraguay | 1β0 | Brazil | H | ITL Β· Copa Oswaldo Cruz |
| 25 Jul 1968 | Paraguay | 0β4 | Brazil | A | ITL Β· Copa Oswaldo Cruz |
| 17 Jul 1968 | Peru | 0β4 | Brazil | A | ITL Β· Friendly |
| 14 Jul 1968 | Peru | 3β4 | Brazil | A | ITL Β· Friendly |
| 10 Jul 1968 | Mexico | 2β1 | Brazil | H | ITL Β· Friendly |
| 07 Jul 1968 | Mexico | 0β2 | Brazil | A | ITL Β· Friendly |
| 30 Jun 1968 | Portugal | 0β2 | Brazil | A | ITL Β· Friendly |
| 25 Jun 1968 | Yugoslavia | 0β2 | Brazil | A | ITL Β· Friendly |
| 23 Jun 1968 | Czechoslovakia | 3β2 | Brazil | H | ITL Β· Friendly |
| 20 Jun 1968 | Poland | 3β6 | Brazil | A | ITL Β· Friendly |
| 16 Jun 1968 | Germany | 2β1 | Brazil | H | ITL Β· Friendly |
| 12 Jun 1968 | Brazil | 4β0 | Uruguay | H | ITL Β· Copa Rio Branco |
| 09 Jun 1968 | Brazil | 2β0 | Uruguay | H | ITL Β· Copa Rio Branco |
| 19 Sep 1967 | Chile | 0β1 | Brazil | A | ITL Β· Friendly |
| 01 Jul 1967 | Uruguay | 1β1 | Brazil | D | ITL Β· Copa Rio Branco |
| 28 Jun 1967 | Uruguay | 2β2 | Brazil | D | ITL Β· Copa Rio Branco |
| 25 Jun 1967 | Uruguay | 0β0 | Brazil | D | ITL Β· Copa Rio Branco |
| 19 Jul 1966 | Brazil | 1β3 | Portugal | A | ITL Β· FIFA World Cup |
| 15 Jul 1966 | Brazil | 1β3 | Hungary | A | ITL Β· FIFA World Cup |
| 12 Jul 1966 | Brazil | 2β0 | Bulgaria | H | ITL Β· FIFA World Cup |
| 30 Jun 1966 | Sweden | 2β3 | Brazil | A | ITL Β· Friendly |
| 25 Jun 1966 | Scotland | 1β1 | Brazil | D | ITL Β· Friendly |
| 15 Jun 1966 | Brazil | 2β2 | Czechoslovakia | D | ITL Β· Friendly |
| 12 Jun 1966 | Brazil | 2β1 | Czechoslovakia | H | ITL Β· Friendly |
| 08 Jun 1966 | Brazil | 3β1 | Peru | H | ITL Β· Friendly |
| 08 Jun 1966 | Brazil | 2β1 | Poland | H | ITL Β· Friendly |
| 05 Jun 1966 | Brazil | 4β1 | Poland | H | ITL Β· Friendly |
| 04 Jun 1966 | Brazil | 4β0 | Peru | H | ITL Β· Friendly |
| 19 May 1966 | Brazil | 1β0 | Chile | H | ITL Β· Friendly |
| 18 May 1966 | Brazil | 1β0 | Wales | H | ITL Β· Friendly |
| 15 May 1966 | Brazil | 1β1 | Chile | D | ITL Β· Friendly |
| 14 May 1966 | Brazil | 3β1 | Wales | H | ITL Β· Friendly |
| 20 Apr 1966 | Chile | 2β1 | Brazil | H | ITL Β· Copa Bernardo O'Higgins |