| Date | Home | Score | Away | R | Tournament |
|---|---|---|---|---|---|
| 17 Apr 1966 | Chile | 0–1 | Brazil | A | ITL · Copa Bernardo O'Higgins |
| 21 Nov 1965 | Brazil | 5–3 | Hungary | H | ITL · Friendly |
| 21 Nov 1965 | Brazil | 2–2 | Russia | D | ITL · Friendly |
| 07 Sep 1965 | Brazil | 3–0 | Uruguay | H | ITL · Friendly |
| 04 Jul 1965 | Russia | 0–3 | Brazil | A | ITL · Friendly |
| 30 Jun 1965 | Sweden | 1–2 | Brazil | A | ITL · Friendly |
| 24 Jun 1965 | Portugal | 0–0 | Brazil | D | ITL · Friendly |
| 17 Jun 1965 | Algeria | 0–3 | Brazil | A | ITL · Friendly |
| 09 Jun 1965 | Brazil | 0–0 | Argentina | D | ITL · Friendly |
| 06 Jun 1965 | Brazil | 2–0 | Germany | H | ITL · Friendly |
| 02 Jun 1965 | Brazil | 5–0 | Belgium | H | ITL · Friendly |
| 07 Jun 1964 | Brazil | 4–1 | Portugal | H | ITL · Friendly |
| 03 Jun 1964 | Brazil | 0–3 | Argentina | A | ITL · Friendly |
| 30 May 1964 | Brazil | 5–1 | England | H | ITL · Friendly |
| 19 May 1963 | Israel | 0–5 | Brazil | A | ITL · Friendly |
| 17 May 1963 | Egypt | 0–1 | Brazil | A | ITL · Friendly |
| 12 May 1963 | Italy | 3–0 | Brazil | H | ITL · Friendly |
| 08 May 1963 | England | 1–1 | Brazil | D | ITL · Friendly |
| 05 May 1963 | Germany | 1–2 | Brazil | A | ITL · Friendly |
| 02 May 1963 | Netherlands | 1–0 | Brazil | H | ITL · Friendly |
| 28 Apr 1963 | France | 2–3 | Brazil | A | ITL · Friendly |
| 24 Apr 1963 | Belgium | 5–1 | Brazil | H | ITL · Friendly |
| 21 Apr 1963 | Portugal | 1–0 | Brazil | H | ITL · Friendly |
| 16 Apr 1963 | Brazil | 5–2 | Argentina | H | ITL · Copa Roca |
| 13 Apr 1963 | Brazil | 2–3 | Argentina | A | ITL · Copa Roca |
| 31 Mar 1963 | Bolivia | 5–4 | Brazil | H | ITL · Copa América |
| 27 Mar 1963 | Brazil | 2–2 | Ecuador | D | ITL · Copa América |
| 24 Mar 1963 | Argentina | 3–0 | Brazil | H | ITL · Copa América |
| 17 Mar 1963 | Brazil | 0–2 | Paraguay | A | ITL · Copa América |
| 14 Mar 1963 | Brazil | 5–1 | Colombia | H | ITL · Copa América |
| 10 Mar 1963 | Brazil | 1–0 | Peru | H | ITL · Copa América |
| 03 Mar 1963 | Paraguay | 2–2 | Brazil | D | ITL · Friendly |
| 17 Jun 1962 | Brazil | 3–1 | Czechoslovakia | H | ITL · FIFA World Cup Final |
| 13 Jun 1962 | Chile | 2–4 | Brazil | A | ITL · FIFA World Cup |
| 10 Jun 1962 | Brazil | 3–1 | England | H | ITL · FIFA World Cup |
| 06 Jun 1962 | Brazil | 2–1 | Spain | H | ITL · FIFA World Cup |
| 02 Jun 1962 | Brazil | 0–0 | Czechoslovakia | D | ITL · FIFA World Cup |
| 30 May 1962 | Brazil | 2–0 | Mexico | H | ITL · FIFA World Cup |
| 16 May 1962 | Brazil | 3–1 | Wales | H | ITL · Friendly |
| 12 May 1962 | Brazil | 3–1 | Wales | H | ITL · Friendly |