| Date | Home | Score | Away | R | Tournament |
|---|---|---|---|---|---|
| 25 May 1966 | Lithuania | 6โ0 | Libya | H | ITL ยท Friendly |
| 10 Apr 1966 | Libya | 6โ1 | Lebanon | H | ITL ยท Arab Cup |
| 09 Apr 1966 | Iraq | 3โ1 | Libya | H | ITL ยท Arab Cup |
| 06 Apr 1966 | Libya | 13โ0 | Yemen | H | ITL ยท Arab Cup |
| 04 Apr 1966 | Libya | 0โ0 | Syria | D | ITL ยท Arab Cup |
| 03 Apr 1966 | Libya | 21โ0 | Oman | H | ITL ยท Arab Cup |
| 01 Apr 1966 | Libya | 0โ0 | Palestine | D | ITL ยท Arab Cup |
| 27 Mar 1966 | Libya | 0โ1 | Malta | A | ITL ยท Friendly |
| 14 Mar 1966 | Libya | 0โ2 | Iraq | A | ITL ยท Friendly |
| 11 Mar 1966 | Libya | 4โ0 | Morocco | H | ITL ยท Friendly |
| 13 Feb 1966 | Malta | 1โ0 | Libya | H | ITL ยท Friendly |
| 19 Mar 1965 | Libya | 1โ0 | Morocco | H | ITL ยท Friendly |
| 14 Mar 1965 | Libya | 4โ1 | Kuwait | H | ITL ยท Friendly |
| 19 Nov 1964 | Kuwait | 1โ1 | Libya | D | ITL ยท Arab Cup |
| 17 Nov 1964 | Iraq | 1โ1 | Libya | D | ITL ยท Arab Cup |
| 16 Nov 1964 | Jordan | 2โ5 | Libya | A | ITL ยท Arab Cup |
| 14 Nov 1964 | Libya | 2โ1 | Lebanon | H | ITL ยท Arab Cup |
| 15 Mar 1964 | Libya | 2โ2 | Malta | D | ITL ยท Friendly |
| 08 Mar 1964 | Libya | 0โ1 | Lebanon | A | ITL ยท Friendly |
| 03 Jun 1962 | Tunisia | 2โ2 | Libya | D | ITL ยท Friendly |
| 11 Mar 1962 | Libya | 6โ3 | Tunisia | H | ITL ยท Friendly |
| 09 May 1958 | Tunisia | 4โ1 | Libya | H | ITL ยท Friendly |
| 03 Apr 1958 | Morocco | 3โ1 | Libya | H | ITL ยท Friendly |
| 02 Jun 1957 | Tunisia | 4โ2 | Libya | H | ITL ยท Friendly |